Let's look at all the different criteria (reflexivity, symmetry or antisymmetry, and transitivity) for the first relations, $aR_1b\Leftrightarrow a=2b$ :
a) Is it reflexive, or antireflexive, or neither? For this we want to test $aR_1a$ — or in other words, whether $a=2a$. This can hold if $a=0$, but otherwise it never holds. So on $\Bbb{Z}$ the relation is neither reflexive nor antireflexive; but on $\Bbb{N}$ (the set of 'whole numbers', not counting 0) it would be antireflexive, since $a=2a$ can never hold there.
b) Is it symmetric, or antisymmetric, or neither? Here we want to compare $aR_1b$ and $bR_1a$ where $a$ and $b$ are distinct values; in other words, can we have both $a=2b$ and $b=2a$? Dividing by 2, the latter is equivalent to $a=\frac{1}{2}b$, and the only way we can have both $a=2b$ and $a=\frac{1}{2}b$ is to have $b=0$, in which case $a=0$ — but since we said that $a$ and $b$ had to be distinct, this can't hold. In other words, if we have $aR_1b$ for $a\neq b$ we can never have $bR_1a$; the relation is antisymmetric.
c) Is it transitive? (Note that we never ask about 'antitransitivity', even though the concept hypothetically makes sense). For this, we want to figure out if $(aR_1b)\wedge(bR_1c)\implies(aR_1c)$ — in other words, if $a=2b$ and $b=2c$, is $a=2c$? Well, if $a=2b$ and $b=2c$, then we have $a=2b=2(2c)=4c$, so it's definitely not the case that $a=2c$; this relation is not transitive.
Since this has the feel of homework, I'll let you do the second one yourself, but it should be relatively straightforward (as long as you know a little bit about divisibility). For looking at reflexivity, you'll have special cases again where $a=0$ and also where $a=\pm1$ to keep an eye out for; for symmetry you should be able to use the divisibility to say something about the relative order of $a$ and $b$; and for transitivity you should try to figure out how to 'staple' the two conditions $a^2|b$ and $b^2|c$ together to see if you can figure out whether $a^2|c$.