The issue comes down to ambiguous terminology.

$(a^b)^c = a^{bc}$, but $a^{(b^c)} \neq a^{bc}$. In other words, exponents aren't associative.

Conventionally, nested exponentials without parentheses are grouped in this second way, because it's more useful. So $2^{2^n} = 2^{(2^n)} \neq 2^{2n}$.

The issue comes down to ambiguous terminology.

$(a^b)^c = a^{bc}$, but $a^{(b^c)} \neq a^{bc}$. In other words, exponents aren't associative.

Conventionally, nested exponentials without parentheses are grouped in this second way, because it's more useful. So $2^{2^n} = 2^{(2^n)} \neq 2^{2n}$. If we wanted to talk about $(2^2)^n$, we could just write $2^{2n}$ instead, so we reserve the double exponential notation for the other case.