You can show this fact by a quick proof by contradiction. If you are not familiar with proof by contradiction, I recommend you read up on it to understand how it works. And you should also know that regular languages are closed under complement. This means that if a language is regular, then its complement must also be regular.
Proof:
We are given that $L$ is non-regular, and we are trying to prove that $\bar{L}$ (complement of $L$) is also non-regular.
We can prove this through proof by contradiction. Let's make the assumption that $\bar{L}$ is regular. Since regular languages are closed under complement, then the complement of $\bar{L}$, that is $\bar{\bar{L}}$, must be regular. But $\bar{\bar{L}} = L$, and we know $L$ should be NOT regular. Therefore we have a contradiction. Therefore our initial assumption that $\bar{L}$ is regular is incorrect, which must mean $\bar{L}$ is non-regular.