Can someone give me the definition of #Monotone-2SAT?

In the decision problem, I set all variables to true and see if the formula is satisfiable.

My question is because I do not understand how there can be multiple solutions, though all variables are true.

In $$\#\text{Monotone-2SAT}$$, the formula is in 2-CNF (conjunctive normal form with at most two literals per clause) and is monotone (there are no negations). So, certainly, making all the variables true satisfies the formula, but there are plenty of other ways. Just consider the formula $$x\lor y$$, which is monotone and in 2-CNF. It has three satisfying assignments.