No, when we talk about dominant terms in big-O notation we talk about asymptotic domination, i.e. how terms scale as $n \to \infty$. To see this you can think about the limit:
$$\lim_{n \to \infty}\frac{f(n)}{g(n)} = C \ .$$
If this value is $C \in \mathbb{R}$, then we have that $f(n)=O(g(n))$ and so the sum $O(f(n))+O(g(n))=O(g(n))$.
If instead, $C=+\infty$, then it's the opposite, i.e. $g(n)=O(f(n))$ and so the sum will be $O(f(n))+O(g(n))=O(f(n))$.
In your case, even if for small values of $n$ it seems that $n^{20}$ grows faster than $3^n$, this is not the case.
Indeed, $\lim_{n\to \infty} \frac{3^n}{n^{20}} = + \infty $.
You can see it in this way: $3^n=(3^{\log_3 n})^{n/\log_3 n}=n^{n/\log_3 n}$ which grows obviously bigger than $n^{20}$, in particular it surpasses $n^{20}$ as soon as the exponent $\frac{n}{\log_3 n}$ surpasses $20$.
It it worth to notice that asymptotic behavior isn't everything. In practice, polynomials with large exponents or large multiplicative constants can be bigger than exponentials for values of $n$ from real world applications.