Regarding $1$:
$$
\text{PARITY}(x_1,x_2,\dots,x_n) = \frac{1}{2} \cdot(1-2x_1) \cdot (1-2x_2) \cdot \ldots \cdot (1-2x_n) + \frac{1}{2}
$$
The idea is that the term $(1-2x_i)$ will be $1$ if $x_i=0$ and $-1$ otherwise. The product of all these terms will have absolute value $1$ and the sign will encode the parity. To map $-1$ and $1$ back to $0$ and $1$ we multiply by $\frac{1}{2}$ and add $\frac{1}{2}$.
Regarding $2$: I'm not sure if this answers the question but every function $f(x_1, x_2, \dots, x_n)$ can be expressed with a polynomial (in $x_1, \dots, x_n$) that is linear in each of the $x_i$.
Let $A = \{ (a_1, \dots, a_n) \in \{-1, 1\}^n \mid f(\frac{a_1}{2}+\frac{1}{2},\dots,\frac{a_n}{2}+\frac{1}{2}) = 1 \}$.
In other words $A$ contains all vectors that encode inputs for which $f$ is $1$, with the convention that "false" is represented by $-1$ and "true" is represented by $1$.
Consider:
$$
\sum_{a_1, \dots, a_n \in A} \prod_{i=1}^n \left( \frac{1}{2} (2x_i-1) a_i + \frac{1}{2} \right)
=
\sum_{a_1, \dots, a_n \in A} \prod_{i=1}^n \left( x_i a_i -\frac{a_i}{2} + \frac{1}{2}\right)
$$
The expression $x_i a_i-\frac{a_i}{2} + \frac{1}{2}$ returns $1$ if $x_i \in \{0,1\}$ and $a_i \in \{-1,1\}$ are both "true" or both "false", and $0$ otherwise. Then the product is $1$ if $x_1,\dots,x_n$ matches $a_1, \dots, x_n$ and $0$ otherwise.
Finally, the whole expression is $1$ if $x_1, \dots, x_n$ matches at least one vector in $A$, and $0$ otherwise.