For a reduction $f:\Sigma^{\ast}_{\Pi_{1}}\rightarrow \Sigma^{\ast}_{\Pi_{2}}$ from language $\Pi_{1}$ to $\Pi_{2}$ to be valid you have to prove that if $I\in \Pi_{1}$ then $f(I) \in \Pi_{2}$ and that if $f(I) \in \Pi_{2}$ then $I\in \Pi_{1}$.
Mathematically, you don't have to show how to get the solution of one from the other, just that if a solution for one exists, then a solution for the other has to as well (in both directions).
Practically of course, a reduction normally has a constructive way of doing this, i.e. if someone gave you the solution for either $I$ or $f(I)$, you would be able to produce the solution for the other.
Now in your specific case, what you would need to show is that, given any 3-SAT instance, if there's a satisfying assignment for the 3-SAT instance, then there's a satisfying assignment for the 2-SAT instance it maps to and vice versa. However I don't see how you can say you've found an assignment for the formulae - the reduction should work for every possible 3-SAT instance (that's the whole point), so there's no way you can know enough about the input to solve it, because it's not a specific, concrete formula.
Or to put it another way, if what you've got is a conversion between a specific boolean formula in 3-CNF to a specific boolean formula in 2-CNF, then you don't have a reduction from 3-SAT to 2-SAT, you only have a mapping between two particular formulae.
Lastly, attempting this reduction doesn't seem productive. This reduction cannot be polynomial-time computable unless $P=NP$. If it is only exponential-time computable, it's possible, but useless because there's a trivial reduction, you can simply solve 3-SAT in that amount of time, there's no need to convert it to a 2-SAT instance then solve that instead.