Some problems such as sorting have famous complexity lower bounds (ex: $O(n \log (n))$ in this case) but I feel that doesn't totally remove the possibility of improving algorithms by shaving constants. Are there any really non trival, perhaps not practical sorts, that have excellent constant performance? For example do there exist algorithms that say achieve $\frac{1}{2} n \log(n)$ number of comparisons as opposed to say mergesorts $1.44 n \log(n)$, and can this leading constant, be reduced arbitrarily low?
It oculd be the case these algorithms have running time
$$ 0.0001 n \log(n) + 9^{\text{Graham's Numbers}}n + \pi^{\pi^\pi} $$
But I am still curious if non trivial reduction of constants exists, or if someone has proven tight bounds on what the constants must be.