Consider the following table:
FirstName LastName Pet FavColour
-----------------------------------
Alice Jones dog red
Alice Smith dog green
Bob Smith cat blue
A key is any set of attributes: any subset of {FirstName, LastName, Pet, FavColour}. The uniqueness property says that no two records can have the same values for the attributes in a key. So, for example, {FavColour} is a key that has the uniqueness property: no two records have the same value for it. {Firstname, Lastname} is also unique: no two records have the same first and last name. {Pet}, on the other hand, is not unique, since the first and second records have the same value for that attribute.
Now, {FirstName, LastName, Pet, FavColour} is also a unique key: no two records have the same value for all the attributes. But that's kind of a silly key, right? Irreducibility says that, if you remove any of the attributes from your key, it stops being unique. So {Firstname, LastName, Pet, FavColour} isn't irreducible because, if you remove FavColour, you get the key {FirstName, LastName, Pet}, which still has uniqueness. And that isn't irreducible because you can throw away Pet and get {FirstName, LastName}, which is still unique. However, {FirstName, LastName} is irreducible because neither {FirstName} nor {LastName} is unique: there are two people with the same first name and two people with the same last name.