Disclaimer: This answer is based on the assumption that $\mbox{PSPACE} \neq \mbox{NP}$,
a hypothesis most scientists strongly believe, but we have yet to prove. This means that there is a possibility that these problems are in $\mbox{NP}$ and thus also $\mbox{NP}$-complete.
I would say the simplest most are True quantified Boolean formula and Generalized geography, both $\mbox{PSPACE}$-complete.
TQBF is given a quantified boolean formula, test whether the formula is true, i.e. formulae on the form $\forall x \exists y \forall z . \; [(x \lor y) \land z]$ is false, because setting $z$ to false yields a false statement.
Generalized Geography is a fun game (see Word chain) where you have a list of strings (e.g. city names) and Player 1 starts by saying a name, and Player 2 responds with a name starting on the letter the previous name ended with. Then it's Player 1's turn, until someone get stuck (this game is recommended to play as a drinking game where objects are bands/artists, movies, cities, capitals, famous mathematicians or whatever floats your boat. The one who cannot respond within reasonable time must of course drink). The formal problem is stated as the question "does Player 1 have a winning strategy".