I tried to solve it as the following: $$\overline{L}=\big\{\langle M_1,M_2\rangle\mid M_1, M_2\text{ are TM and } L(M_1)\cup L(M_1)\neq\Sigma^* \big\}$$ I'll show that $\overline{L}\not\in RE$ by reduction from $$\overline{A_{TM}} = \big\{ \langle M, w \rangle \mid M \text{ is TM and }M \text{ rejects } w \big\}$$ I begin by assuming that $\overline{L}$ is recognized by some TM $M'$.
Next, I construct a machine $M_{\overline{A_{TM}}}$ that will use $M'$ to recognize $\overline{A_{TM}}$.
TM $M'$ on input $\langle M, w\rangle$:
Build TM $M_1,M_2$
Simulate $M_1,M_2$ on all $x\in\Sigma^*$, Any simulation will be at most $|x|$ steps.
If $M_1$ and $M_2$ reject the same $x$, then $M'$ will accept $\langle M, w\rangle$.
If $M_1$ or $M_2$ accept some $x$, then $M'$ will reject $\langle M, w\rangle$.
Therefore, $\langle M, w \rangle\in\overline{A_{TM}}$ exactly when $\langle M_1,M_2\rangle\in\overline{L}$.
Because $\overline{A_{TM}}\not\in RE$ so is $\overline{L}$, then $L\not\in co-RE$
Is it true and can I use similar approach to show that $L\not\in RE$?
Thanks.