For the coin values: 1, 3, 9, 27, suppose $16 = a_0 + 3a_1 + 9a_2 + 27a_3$ is the coin exchange with minimal number of coins. Note that $16\equiv a_0 \equiv 1(\operatorname{mod}3)$. If $a_0 \ge 3$, then we can subtract 3 from $a_0$ and add 1 to $a_1$ to obtain coin exchange with less number of coins. So, $a_0$ must be the remainder of 16 divided by 3. Hopefully, you can see where I am going.
All numbers or variables below are nonnegative integers. $(d_nd_{n-1}\cdots d_0)_a$ means the integer with those digits in base $a$, i.e., $(d_nd_{n-1}\cdots d_0)_a=\sum_{i=0}^{n}d_ia^i$ where $d_i\lt a $ for $i\le n$.
Here is the general theorem.
(Greedy algorithm works for power coins) Let $a\ge2$ and $n\ge0$. If $e_na^n+(e_{n-1}e_{n-2}\cdots e_0)_a=\sum_{i=0}^nc_ia^i$, then $ \sum_{i=0}^ne_i\le\sum_{i=0}^nc_i$.
Proof by mathematical induction on $n\ge0$.
The base case, when $n=0$ is trivial.
Suppose it is true for some $n\ge0$. Let us check the case of $n+1$. Suppose $m=e_{n+1}a^{n+1}+(e_ne_{n-1}\cdots e_0)_a=\sum_{i=0}^{n+1}c_ia^i$. Note that $e_0$ is the remainder of $m$ divided by $a$.
If $c_{0}\ge a$, we can subtract $a$ from $c_0$ and add $1$ to $c_1$ to reduce sum $\sum_{i=0}^{n+1}c_i$. Without loss of generality we can assume $c_{0}\lt a$, i.e., $c_0$ is also the remainder of $m$ divided by $a$.
Now let $m'=(m-e_0)/a=(m-c_0)/a$. Then $m'=e_{n+1}a^{n}+(e_{n}e_{n-1}\cdots e_1)_a=\sum_{i=0}^{n}c_{i+1}a^i$. By induction hypothesis, we know $\sum_{i=0}^ne_{i+1}\le\sum_{i=0}^nc_{i+1}$. Adding $e_0=c_0$ to both sides, we obtained the wanted inequality for the case of $n+1$. Q.E.D.
What is left to be explained is that $\sum_{i=0}^ne_i$ does
come from the greedy algorithm. That easy task will be left for interested readers to verify.