The substitution method for recurrence solving wants you to come up with a guess function $g(n)$ which has the property $g(n) \in O(f(n))$. The goal is to show that your recurrence $T(n) \in O(f(n))$. In order to do that, you claim $T(n) \leq g(n)$ and substitute accordingly until you have that exact term.
Example: $$T(n) = 2T(n/2) + n$$ $$T(n) \leq cn^2 - dn$$
Substitution: $$T(n/2) \leq c(n/2)^2 - (d/2)n = (c/4)n^2 - (d/2)n$$
So: $$T(n) = 2T(n/2) + n$$ $$T(n) \leq 2[(c/4)n^2 - (d/2)n]+n$$ $$T(n) \leq (c/2)n^2 - dn+n$$
Multiply with 2, property is not violated. $$T(n) \leq cn^2 - 2dn + 2n$$
If we assume $d \geq 2$ $$T(n) \leq cn^2 - dn$$
Our function $g(n) = cn^2 - dn$ and we tried to show that $T(n) = O(n^2)$ because $g(n) \in O(n^2)$.
Assume we failed to do the proof this well and we got something like: $$T(n) \leq (ac + b)n^2 - (xd+y)n$$
Observe that $a, b, c, d, x, y$ are all constants.
Would it be possible to claim $(ac + b) = c_2$ and $(xd+y) = d_2$?
Is this new expression $c_2n^2 - d_2n$ another function $g_2(n) \in O(n^2)$?
Would this indirectly still prove that $T(n)\in O(n^2)$?