I was wondering whether it is possible (and if so, then how) to tell what is the maximum number of equivalence classes generated by a DFA as per Myhill-Nerode theorem (assuming it has no redundant transitions) as a function of number of accepting and rejecting states and cardinality of its alphabet.
My guess is that it should be something like $\log(n) \cdot |{\Sigma}|$, where $n$ is the number of states, since one could see this as tree of derivations created by something like left-regular grammar equivalent to the same automata, and classes would be the leafs of this tree. But this is just a guess.