The flaw in your approach is that you assume that the second level contains only $2$ and $3$. The following examples is min heap with $3$ not in the second level.
1
/ \
2 5
/ \ / \
3 4 6 7
The solution is available here.
Solution:
The root of the tree has to be the minimum element, therefore $1$ is at the root.
Now we need to find the possible ways to fill the left and right subtrees with the remaining $6$ elements. Each of the subtrees contain three elements. For the left subtree we can choose $3$ elements from $6$ elements in $\binom{6}{3}$ ways and the remaining three elements fill the right subtree.
Now in each of these subtrees the root would be the minimum of the three elements that comprise each of these subtrees. However, the two lowest elements in each of these subtrees can be interchanged. Therefore each of the subtrees can exists in two different configurations.
Therefore the total possible configurations would be:
$\binom{6}{3} \times 2 \times 2 = 80$.