how do you call the individual alternatives within the RHS?
As @Rafael mentioned, they are called alternatives.
Parsing Techinques: A Practical Guide, 2nd ed. (2008) by D. Grune and C.J.H. Jacobs, page 15:
There is a more compact notation, in which several right-hand sides for one and the same left-hand side are grouped together and then separated by vertical bars, |. This bar belongs to the formalism, just as the arrow $\to$, and can be read “or else”. The right-hand sides separated by vertical bars are also called alternatives.
Is it related to your syntactic forms?
From the same source (p. 13):
Non-terminals [S
, A
, B
, C
in the example] are called (grammar) variables or syntactic categories in linguistic contexts.
It seems the terms syntactic form and syntactic category are used somewhat interchangeably.
So, if an alternative is a variable, then it represents a syntactic form, but if it has more complex structure (it can contain terminals, or several non-terminals), then we might say that from the point of view of the grammar's author the alternative does not represent a syntactic form. But someone else can always turn it into one by defining a new non-terminal with an appropriate RHS.
Since B.C. Pierce's syntactic forms include terminals (true
, false
, 0
), I agree with the accepted answer that the term syntactic form is used somewhat informally and is not defined precisely.