I proved that $$ \{ 0^n 1^{5n} \mid n \geq 0 \}$$ is not a regular language using Pumping Lemma by following way.
Solve by contradiction that $ L = \{0^n 1^{5n} \mid n \geq 0 \}$ is regular language.
Let $0^p 1^{5p}$ be in L, where $p$ is the pumping length.
Now here if the language $L$ is regular language, $0^p 1^{5p}$ can be represented in the form $xyz$ where $|xy| \le p$ & $|y|\gt0$.
Thus, from step 2, we can say that $xy = 0^p$ and $y = 0^j$.
So, $xyz = (0^{p-j})(0^j)(1^{5p})$.
Now pumping the value of y to 2, $xyyz = (0^{p-j})(0^j)(0^j)(1^{5p}) = (0^{p+j})(1^{5p})$, which is surely not in $L$, thus not a regular language.
But how to prove for condition $\{0^n 1^{5n} \mid n \ge 10000 \}$ & for also $n \le 10000$, we can just prove that one of them is not regular and obviously by rules the complement will also be not regular.